Molten-Salt Methane Pyrolysis Optimization Through in-situ Carbon Characterization andReactor Design
Program:
Exploratory Topics
Exploratory Topics
Award:
$1,997,532
$1,997,532
Location:
Santa Barbara, California
Santa Barbara, California
Status:
ALUMNI
Project Term:
05/01/2020 - 04/30/2022
05/01/2020 - 04/30/2022
Critical Need:
This topic would develop high value methane pyrolysis, including approaches that can economically convert natural gas to both fuel cell-grade hydrogen and higher value carbon materials (e.g., carbon fiber) with a low CO2 footprint. The emphasis of these projects is to identify scalable approaches to the development of fuel cell-grade hydrogen, while also advancing the identification, understanding, and control of new reaction conditions and processes necessary to direct carbon formation. The United States currently produces roughly 10 million tons of hydrogen per year from two processes: steam methane reforming that converts natural gas and water into hydrogen and carbon dioxide, and electrolysis of water to hydrogen and oxygen. Both of these traditional methods provide for the production of hydrogen with little or no release of carbon dioxide (through CO2 capture and sequestration in the steam methane process), but there is an inherent opportunity in hydrogen production process to create useful carbon byproducts. Developing high value methane pyrolysis becomes comparably more favorable and economically beneficial when it creates a viable carbon byproduct.
Project Innovation + Advantages:
C-Zero will develop a novel process for transforming methane into hydrogen and valorized carbon cement additive using high temperature liquids in a multi-phase pyrolysis reactor. Unlike current hydrogen generation technologies, C-Zero’s process will not directly coproduce carbon dioxide CO2 and does not require water as an input. If successful, this technology will allow C-Zero to significantly reduce the cost of hydrogen and accelerate large-scale, domestic hydrogen production with low carbon footprint.
Contact
ARPA-E Program Director:
Dr. Jack Lewnard
Project Contact:
Prof. Eric McFarland
Press and General Inquiries Email:
ARPA-E-Comms@hq.doe.gov
Project Contact Email:
eric.mcfarland@czero.energy
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• Ultrasonic Technology Solutions - Extremely Fast and Efficient Direct Contact Ultrasonic Drying for Roll To Roll Manufacturing
• University of California, Berkeley (UC Berkeley) - Ligand Facilitated Bioaccumulation: Biomining of Rare Earth and Other Critical Metals from Electronic Wastes
• University of California, Davis (UC Davis) - Electron Density Profile Measurements Using USPR
• University of California, Davis (UC Davis) - Carbon-Negative Buildings Assessment and Tool (CaNBAT)
• University of California, Los Angeles (UCLA) - Low-Temperature Architected Cementation Agents (LAMINAE)
• University of California, San Diego (UC San Diego) - Extremely Durable and Low-Cost Concrete: Ultralow Binder Content and Ultrahigh Tensile Ductility
• University of Colorado, Boulder (CU-Boulder) - Geopolymer Cements: Resistance-Engineered Sewer Infrastructure For Longevity Using Innovative, Energy-Efficient, Synthesis Techniques (RESILIENT)
• University of Connecticut - Detection and Fixation - A Lifecycle-management Framework Towards an SF6-Free Green Power Network
• University of Connecticut - Topology Optimization Of Additively Manufactured Heat-Exchanger Plates For Enhanced Performance (TOP-HEX)
• University of Florida - Boron Concrete For Active Formation of Lithium As Mitigation of Neutron-Induced Expansion and Passive Neutron Absorption
• University of Illinois, Urbana-Champaign (UIUC) - Midwest Bioenergy Crop Landscape Laboratory (MBC-Lab): Capturing Spatio-temporal and Managerial Variations to Provide a Gold Standard Data and Platform for Validating Field-level Emission from Bioenergy Crops
• University of Illinois, Urbana-Champaign (UIUC) - Rapid AI-based Dissection of Ashes using Raman and XRF Spectroscopy (RADAR-X)
• University of Kentucky - Belite Cement, and Concretes; Novel Low-Energy Approaches To Making Concrete Extremely Durable
• University of Michigan - Development of an Extremely Durable Concrete (EDC) - A Novel Approach Coupling Chemistry and Autogenous Crack Width Control
• University of Michigan - Systematic Evaluation of Claims Of Excess Heat Generation Form Deuteration Of Palladium-Nickel Nanocomposites
• University of Michigan - Electrochemical Direct Air Capture of CO2 Using Redox-Active Textiles
• University of Michigan - Ionizing Radiation Detection for Exploratory Experiments In Low-Energy Nuclear Reactions
• University of Nebraska, Lincoln (UNL) - Novel Commercial Farm-field Network to Quantify Emissions and Carbon Storage from Agricultural Bioenergy Feedstock Production
• University of Nebraska, Lincoln (UNL) - Extrapolation Domains for Aggregating Environmental Outcomes from Local to Regional Levels
• University of North Dakota Energy & Environmental Research Center (UND-EERC) - Hydrolytic Softening of Ocean Water for Carbon Dioxide Removal
• University of Rochester Laboratory for Laser Energetics - LLE Diagnostic Resource Team for the Advancement of Innovative Fusion Concepts
• University of Tennessee, Knoxville (UT) - Ultra-Light Tightly-Integrated Modular Aviation-Transportation Enabling Solid-State Circuit Breaker (ULTIMATE-SSCB)
• University of Texas at Austin (UT Austin) - Nanotechnology-Enabled Transformer Life Extension
• University of Utah - Self-Sustaining Cementitious Systems in Roman Reactive Glass Concretes
• University of Washington (UW) - Parametric Open Data for Life Cycle Assessment
• University of Wisconsin-Madison (UW-Madison) - Multi-Physics Topology Optimization and Additive Manufacturing for High-Temperature Heat Exchangers
• Verdox - Electro-swing Adsorption for High Efficiency Direct Air Capture
• Verne - Decoupling High-Density Hydrogen from the Liquid Hydrogen Infrastructure: Catalyst-Filled Heat Exchangers for Modular Cryo-Compressors
• Virginia Polytechnic Institute and State University (Virginia Tech) - High Power Density Cost-Effective MV DC Aircraft Cable
• Virginia Polytechnic Institute and State University (Virginia Tech) - Physical, Chemical, and Mineralogical Characterizations of MSWI Ash Product and Recommendations for Downstream Processing
• Washington State University (WSU) - Biopolymer Modified Cementitious Systems with Radically Superior Strength and Durability
• Western Research Institute - Polymer/Oil Co-processing to Yield Liquid Products (MEME-CCS)
• XFlow Energy - Low-Cost Wind Energy Through Dense VAWT Arrays: Fatigue Loads and Power Performance Risk Mitigation
• Zephyr Innovations - Air Conditioning via Liquid Desiccant Dehumidification
Release Date:
09/26/2019