Co-Synthesis of Hydrogen and High-Value Carbon Products from Methane Pyrolysis
Program:
Exploratory Topics
Exploratory Topics
Award:
$1,877,548
$1,877,548
Location:
Stanford, California
Stanford, California
Status:
ACTIVE
Project Term:
04/13/2020 - 10/12/2023
04/13/2020 - 10/12/2023
Critical Need:
This topic would develop high value methane pyrolysis, including approaches that can economically convert natural gas to both fuel cell-grade hydrogen and higher value carbon materials (e.g., carbon fiber) with a low CO2 footprint. The emphasis of these projects is to identify scalable approaches to the development of fuel cell-grade hydrogen, while also advancing the identification, understanding, and control of new reaction conditions and processes necessary to direct carbon formation. The United States currently produces roughly 10 million tons of hydrogen per year from two processes: steam methane reforming that converts natural gas and water into hydrogen and carbon dioxide, and electrolysis of water to hydrogen and oxygen. Both of these traditional methods provide for the production of hydrogen with little or no release of carbon dioxide (through CO2 capture and sequestration in the steam methane process), but there is an inherent opportunity in hydrogen production process to create useful carbon byproducts. Developing high value methane pyrolysis becomes comparably more favorable and economically beneficial when it creates a viable carbon byproduct.
Project Innovation + Advantages:
Stanford University will design a process for catalytic pyrolysis of methane into high-value carbon nanotubes and hydrogen (H2) at the low cost of $1/kg, without any carbon dioxide (CO2) emissions. This project will synthesize high-performance, nano-controlled pyrolysis catalysts with structural features that enable efficient catalyst regeneration and separation of solid crystalline carbon. The carbon nanotubes can be used in a wide range of applications from batteries to carbon-fiber composites. Low-cost, CO2-free hydrogen can be used to decarbonize multiple large industries such as refinery and petrochemicals, ammonia production, steel, concrete, and transportation.
Contact
ARPA-E Program Director:
Dr. Jack Lewnard
Project Contact:
Matteo Cargnello
Press and General Inquiries Email:
ARPA-E-Comms@hq.doe.gov
Project Contact Email:
mcargn@stanford.edu
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• Oklahoma State University (OSU) - Establishing Validation Sites for Field-Level Emissions Quantification from Grain Sorghum in Southern Great Plains
• Oregon State University (OSU) - Development of Thermodynamic and Kinetic Simulation Tools and Testing Procedures For Enhanced Durability of Concrete Containing Industrial By-Products
• Origen Hydrogen - Engineering of Scalable Platinum-free Electrodes for Pure-Water AEM Water Electrolysis
• Osmoses - Efficient Recovery of Dilute Helium Gas Using Molecular Sieve Membranes
• Otherlab - SeaSTAR: Selective Thalassic Ambulatory Retriever
• Pacific Industrial Development Corporation - Biomimetic CO2 to Fuel Enabled by Scalable Catalyst Development and Synthetic Electrochemistry
• Pacific Northwest National Laboratory (PNNL) - UNrealized Critical Lanthanide Extraction via Sea Algae Mining (UNCLE-SAM): Domestic production of critical minerals from seawater
• Pennsylvania State University (Penn State) - Synthesis of Consists as Rolling Energy micro-grids (SCORE)
• Pennsylvania State University (Penn State) - Cryogenic Solid-state Circuit Breaker
• Perseus Materials - Variable Cross-sectional Casting: New Composite Fabrication Process for Wind Turbine Blades
• pH Matter - Type V Vessel-Aided Electrochemical Compression for Ultra-High Pressure Electrolysis
• Phoenix Tailings - Novel Technique for Domestic Rare Earth Oxide Separation and Rare Earth Metal Reduction
• Phytodetectors - Functional Engineering of a Photosynthetic Desalination Pump Circuit
• Princeton Plasma Physics Laboratory (PPPL) - A Portable Ion-Energy Diagnostic for Transformative ARPA-E Fusion Energy R&D
• Princeton University - Highly Efficient Charged Particle Beam Injection into Magnetically Confined Plasmas
• Princeton University - Electricity System Capacity Expansion and Operational Modeling for Evaluation and Optimization of Flexible Carbon Capture and Sequestration Systems
• Raytheon Technologies Research Center - Multi-Material Topology Optimization for High Performance Heat Exchangers
• Rutgers University - Waste-to-Energy (WTE)-Derived Low-Carbon-Footprint Concrete (LCFC)
• Sequoia Scientific - Real-time, In-situ Sensing of Sediment Properties for Environmental Monitoring of Deep-Sea Polymetallic Nodule Mining Real-time, In-situ Sensing of Sediment Properties for Environmental Monitoring of Deep-Sea Polymetallic Nodule Mining
• Siemens - Multi-Physics Topology Optimization for Dual Flow Heat Exchangers
• SiTration - Low-Cost Recycling of Lithium from Batteries via Conductive Membrane Nanofiltration
• Southern Research Institute - Machine Learning for Automated Maintenance of Future MSR
• Stanford University - Nuclear Product Detection from Deuterated Nanoparticles under Phonon Stimulation
• Stanford University - Co-Synthesis of Hydrogen and High-Value Carbon Products from Methane Pyrolysis
• Stoicheia - Discovery Platform for Low-Ir Anode Catalysts in PEM Electrolyzers
• Sublime Systems - Electrochemical Synthesis of Low-Carbon Cement
• Sylvatex - Breakthrough Process to Manufacture Very Low-cost LFP Cathode for Li-ion Batteries
• Texas Tech University - Advanced Materials Characterization and Nuclear Product Detection for LENR
• Texas Tech University - Development of Cubic Boron Nitride (c-BN) Ultrawide Bandgap Semiconductors
• The Boeing Company - Multidisciplinary Topology Optimization of Extreme Environment Heat Exchangers
• The City College of New York - Gypsum & Clay-Based Additives to MSW for Pre-Combustion Enhancement of Syngas and Solid Residue Improvement
• Tufts University - Living Filter Design for High-throughput, Low-cost Recovery of Critical Materials
• UHV Technologies - Highly Efficient Vacuum Smelting of Aluminum
• Ultra-low Loss Technologies - Space Division Multiplexing with Multi-Core Fiber for Energy Efficient Integrated Photonic Networking Technologies
• Ultrasonic Technology Solutions - Extremely Fast and Efficient Direct Contact Ultrasonic Drying for Roll To Roll Manufacturing
• University of California, Berkeley (UC Berkeley) - Ligand Facilitated Bioaccumulation: Biomining of Rare Earth and Other Critical Metals from Electronic Wastes
• University of California, Davis (UC Davis) - Electron Density Profile Measurements Using USPR
• University of California, Davis (UC Davis) - Carbon-Negative Buildings Assessment and Tool (CaNBAT)
• University of California, Los Angeles (UCLA) - Low-Temperature Architected Cementation Agents (LAMINAE)
• University of California, San Diego (UC San Diego) - Extremely Durable and Low-Cost Concrete: Ultralow Binder Content and Ultrahigh Tensile Ductility
• University of Colorado, Boulder (CU-Boulder) - Geopolymer Cements: Resistance-Engineered Sewer Infrastructure For Longevity Using Innovative, Energy-Efficient, Synthesis Techniques (RESILIENT)
• University of Connecticut - Detection and Fixation - A Lifecycle-management Framework Towards an SF6-Free Green Power Network
• University of Connecticut - Topology Optimization Of Additively Manufactured Heat-Exchanger Plates For Enhanced Performance (TOP-HEX)
• University of Florida - Boron Concrete For Active Formation of Lithium As Mitigation of Neutron-Induced Expansion and Passive Neutron Absorption
• University of Illinois, Urbana-Champaign (UIUC) - Midwest Bioenergy Crop Landscape Laboratory (MBC-Lab): Capturing Spatio-temporal and Managerial Variations to Provide a Gold Standard Data and Platform for Validating Field-level Emission from Bioenergy Crops
• University of Illinois, Urbana-Champaign (UIUC) - Rapid AI-based Dissection of Ashes using Raman and XRF Spectroscopy (RADAR-X)
• University of Kentucky - Belite Cement, and Concretes; Novel Low-Energy Approaches To Making Concrete Extremely Durable
• University of Michigan - Development of an Extremely Durable Concrete (EDC) - A Novel Approach Coupling Chemistry and Autogenous Crack Width Control
• University of Michigan - Systematic Evaluation of Claims Of Excess Heat Generation Form Deuteration Of Palladium-Nickel Nanocomposites
• University of Michigan - Ionizing Radiation Detection for Exploratory Experiments In Low-Energy Nuclear Reactions
• University of Michigan - Electrochemical Direct Air Capture of CO2 Using Redox-Active Textiles
• University of Nebraska, Lincoln (UNL) - Novel Commercial Farm-field Network to Quantify Emissions and Carbon Storage from Agricultural Bioenergy Feedstock Production
• University of Nebraska, Lincoln (UNL) - Extrapolation Domains for Aggregating Environmental Outcomes from Local to Regional Levels
• University of North Dakota Energy & Environmental Research Center (UND-EERC) - Hydrolytic Softening of Ocean Water for Carbon Dioxide Removal
• University of Notre Dame - GaN Core-shell Nanofin Vertical Transistor (CoNVerT): A New Direction for Power Electronics
• University of Rochester Laboratory for Laser Energetics - LLE Diagnostic Resource Team for the Advancement of Innovative Fusion Concepts
• University of Tennessee, Knoxville (UT) - Ultra-Light Tightly-Integrated Modular Aviation-Transportation Enabling Solid-State Circuit Breaker (ULTIMATE-SSCB)
• University of Texas at Austin (UT Austin) - Nanotechnology-Enabled Transformer Life Extension
• University of Utah - Self-Sustaining Cementitious Systems in Roman Reactive Glass Concretes
• University of Washington (UW) - Parametric Open Data for Life Cycle Assessment
• University of Wisconsin-Madison (UW-Madison) - Multi-Physics Topology Optimization and Additive Manufacturing for High-Temperature Heat Exchangers
• Verdox - Electro-swing Adsorption for High Efficiency Direct Air Capture
• Verne - Decoupling High-Density Hydrogen from the Liquid Hydrogen Infrastructure: Catalyst-Filled Heat Exchangers for Modular Cryo-Compressors
• Virginia Polytechnic Institute and State University (Virginia Tech) - High Power Density Cost-Effective MV DC Aircraft Cable
• Virginia Polytechnic Institute and State University (Virginia Tech) - Physical, Chemical, and Mineralogical Characterizations of MSWI Ash Product and Recommendations for Downstream Processing
• Washington State University (WSU) - Biopolymer Modified Cementitious Systems with Radically Superior Strength and Durability
• Western Research Institute - Polymer/Oil Co-processing to Yield Liquid Products (MEME-CCS)
• WH-Power - Low Cost All Temperature Zinc-pulp Battery for Stationary Storage
• XFlow Energy - Low-Cost Wind Energy Through Dense VAWT Arrays: Fatigue Loads and Power Performance Risk Mitigation
• Zephyr Innovations - Air Conditioning via Liquid Desiccant Dehumidification
Release Date:
09/26/2019